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Authors: Iatsunskyi I., Nowaczyk G., Jurga S., Fedorenko V., Pavlenko M., Smyntyna V. |
Title: One and two-phonon Raman scattering from nanostructured silicon |
Source: Optik |
Year : 2015 |
Abstract:
Raman scattering from highly/low resistive nanostructured silicon films prepared by metal-assisted chemical etching was investigated. Raman spectrum of obtained silicon nanostructures was measured. Interpretation of observed one and two-phonon Raman peaks are presented. First-order Raman peak has a redshift and broadening. This phenomenon is analyzed in the framework of the phonon confinement model taking into account mechanical stress effects. Second-order Raman peaks were found to be shifted and broadened in comparison to those in the bulk silicon. The peak shift and broadening of two-phonon Raman scattering relates to phonon confinement and disorder. A broad Raman peak between 900 and 1100 cm(-1) corresponds to superposition of three transverse optical phonons similar to 2TO (X), 2TO (W) and 2TO (L). Influence of excitation wavelength on intensity redistribution of two-phonon Raman scattering components (2TO) is demonstrated and preliminary theoretical explanation of this observation is presented. (C) 2015 Elsevier GmbH. All rights reserved.
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DOI: 10.1016/j.ijleo.2015.05.088 (Pobrane: 2018-03-29)
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