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wizyta

od 2020-09-20


1.

Szcześniak E., Głowinkowski S., Suchański W., Jurga S.

Dynamics of glass-forming di-n-butyl phthalate as studied by NMR Spin-lattice relaxation times T-1 and nuclear Overhauser effect (NOE) enhancement factors for the individual ring carbons in di-n-butyl phthalate (DBF) show that the reorientational correlation function corresponding to the global dynamics in supercooled liquid can be described by a Davidson-Cole distribution. Measurements of proton spin-lattice relaxation times T-1 and T-1p, as well as H-1 NMR spectra at temperatures below the glass transition temperature, Tg, reveal that the same distribution holds also for description of local dynamics in glassy DBF. The activation parameters of the motions detected are derived.
(C) 1997 Elsevier Science B.V.

Solid State Nuclear Magnetic Resonance, 8(2), 73-79, (1997)

DOI: 10.1016/S0926-2040(96)01292-1   (Pobrane:  2020-10-21)

2.

Paluch M., Zioło J., Habdas P., Rzoska S.J., Suchański W.

Dielectric relaxation of glass-forming dibutyl phthalate under high pressure Measurements of complex electric permittivity in dibutyl phthalate for a wide range of pressures (up to 260 MPa) for isotherm T/K = 243 were performed. Relaxation times calculated from these measurements obey the generalised Vogel - Fulcher - Tammann law. It has been noticed that the full widths at half maximum of absorption curves increase with increasing pressure. Half-widths for isothermal and for isobaric measurements for the same relaxation times were compared. Dixon scaling of absorption curves for isothermal and isobaric data is also presented.

High Temperatures - High Pressures, 29(2), 155-157, (1997)

DOI: 10.1068/htec386   (Pobrane:  2021-12-23)

3.

Głowinkowski S., Jurga S., Suchański W., Szcześniak E.

Local and global dynamics in the glass-forming di-isobutyl phthalate as studied by 1H NMR Spin-lattice relaxation times T-1 and T1ρ as well as H-1 NMR spectra have been employed to study the dynamics of the glass-forming di-isobutyl phthalate in the temperature range extending from 100 K, through the glass transition temperature Tg, up to 340 K. Below Tg NMR relaxation is governed by local dynamics and may be attributed to rotation of methyl groups at low temperatures and to motion of isobutyl groups in the intermediate temperature interval. Above Tg the main relaxation mechanism is provided by overall molecular motion. The observed relaxation behavior is explained by motional models assuming asymmetrical distributions of correlation times. The motional parameters obtained from Davidson-Cole distribution, which yields the best fit of the data at all temperatures are given.
(C) 1997 Elsevier Science B.V.

Solid State Nuclear Magnetic Resonance, 7(4), 313-317, (1997)

DOI: 10.1016/S0926-2040(96)01266-0   (Pobrane:  2020-10-23)

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